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The French superstar was thwarted by Mallorca goalkeeper Dominik Greif and after Rodrygo Goes sent Madrid ahead early on the hosts levelled in the second half through Vedat Muriqi's towering header.
Madrid's star-studded side struggled to break down Mallorca, who came closer to winning the game in the final stages at Son Moix stadium. Los Blancos defender Ferland Mendy was sent off in stoppage time for a high challenge on Muriqi.
Real Madrid coach Carlo Ancelotti selected the same starting line-up which defeated Atalanta to win the UEFA Super Cup on Wednesday, with Jude Bellingham in midfield behind the Mbappe, Vinicius Junior and Rodrygo attacking line.
Mallorca coach Jagoba Arrasate was facing his first match in charge of the Copa del Rey runners-up and could not have asked for a tougher challenge on paper than the reigning champions, bolstered by Mbappe's arrival.
