Jurgen Klopp's injury-hit side finished a gruelling clash with a host of raw youngsters on the pitch, but it was their experienced captain who clinched the club's 10th League Cup triumph. Van Dijk earlier had a goal controversially disallowed by VAR, but the Dutch defender pounced to nod home with just two minutes left.
It was Liverpool's first trophy following Klopp's bombshell announcement that he will step down at the end of this season. The German will hope Liverpool's first silverware since the 2022 FA Cup will be the springboard for an incredible farewell tour.
Quadruple-chasing Liverpool sit top of the Premier League, face Southampton in the FA Cup fifth round on Wednesday and take on Sparta Prague in the Europa League last 16. It was another bitter Wembley experience for Chelsea, who lost the 2022 League Cup and FA Cup finals against Liverpool.