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Igor Tudor resigned after one season in charge in which he took OM to a third-placed finish in Ligue 1 and a spot in the Champions League qualifying rounds. Marcelino will be coaching outside his native Spain for the first time, in his first job since leaving Athletic Bilbao last year.
"It is a very important challenge to be at a big European club, a historic club, the only French club to have a Champions League in its trophy cabinet," the 57-year-old told a press conference.
"Its history gives us the values and the culture to follow, a philosophy that we share. We know the demand of the supporters and our ambition is that they will be proud of this team."
Marseille have not won a major trophy since lifting the now defunct Coupe de la Ligue in 2012.
