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The former PSG forward, signed in August for a reported 90 million euros, grabbed the second in the record Asian champions' win at the Azadi Stadium.
The goal, a sweeping left-footed finish on 58 minutes, represented Neymar's first for Hilal in five matches. Former Fulham striker Aleksandar Mitrovic had opened the scoring on 18 minutes with a header, with substitute Saleh Al Shehri securing the result in injury-time to lift the four-time winners, runners-up last year, top of Group D.
Navbahor, 2022 Uzbekistan Super League runners-up and Champions League debutants, had earlier on Tuesday secured a 3-0 win at home to India's Mumbai City in Namangan.
Both Hilal and Nassaji Mazandaran were forced to play the majority of the match in the Iranian capital with 10 men, after the Saudi side's captain Salman Al Faraj was sent off alongside Amir Houshmand seven minutes before half-time - both for violent conduct.
