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The Croatia international has ended a six-year spell at Anfield after making just 15 appearances this season, falling to fourth-choice centre-back.
Lovren, who was troubled with niggling injuries over the last two years, was set to enter the final year of his contract but Liverpool chose not to take up an option they had for a 12-month extension.
"Another Liverpool legend who leaves the club, because he was absolutely a very, very important part of this team from the first day since I was in," Manager Jurgen Klopp told liverpoolfc.com.
"When he was fit, he was very, very, very often in the team. A great player and a great person. Really good, in the air a machine, and I really liked working together with him. It will be interesting to follow Zenit St. Petersburg now. I wish him the best of luck".
