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Borussia Dortmund defeated Ulsan HD 1-0 to claim top spot in Group F and the Germans will face Sergio Ramos' Monterrey, who thrashed Urawa Red Diamonds 4-0.
Three goals in a nine-minute first half spell helped Monterrey defeat Urawa at the Rose Bowl in Pasadena in front of a crowd of only 14,000.
Nelson Deossa smashed home a spectacular long-distance effort to open the scoring and German Berterame rolled the second in at the far post.
Former Porto winger Jesus Corona walloped home the third with another fine effort from over 30 yards out, and Berterame struck again late on, as the Japanese side departed with three defeats.
"This is what we were looking for, we gave everything - from the first match until this one, they've all been tough," said Berterame. Monterrey face Dortmund in Atlanta on Tuesday.
