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The Italian side raced into a two-goal lead with superb strikes from Marcus Thuram and Denzel Dumfries, before the unstoppable Lamine Yamal pulled Barca back into it with a sublime solo effort.
Ferran Torres levelled for the five-time champions, and although Inter nosed ahead through Dumfries again, a Yann Sommer own goal left the tie on a knife-edge at the halfway stage.
Inter were desperately hoping Thuram would be fit to play after a thigh injury, and he showed precisely why, scoring the fastest ever Champions League semi-final goal after 30 seconds.
Yamal looped a second strike onto the crossbar later on, but the sides could not be separated. The second leg takes place in Milan next Tuesday, with the winner to face Paris Saint-Germain or Arsenal on May 31 in the Munich final.
